Background
Near-infrared (NIR) spectroscopy is a spectroscopic method that uses the near-infrared region of the electromagnetic spectrum (from about 700 nm to 2500 nm).
The spectral features seen in spectra collected from rock are overtones of the fundamental absorption features in the mid-infrared. These spectral features are the result of electronic and vibrational processes in mineral lattices.
The position of features varies dependent upon the substitution of elements in the mineral lattice. For example, a substitution of Mg for Ca in calcite results in a shift of wavelength in the 2300 nm region and is a leading indicator that can be used to track the level of dolomitisation of the limestone.